We aimed to synthesize a new antibacterial agents that will combine the features of nanostructures, supramolecular compounds and polymers. Antibacterial agents consist from 3 types of nanosupramolecular complexes (occurred from interaction of 3 different crown-ether, polymer, nanoparticles) according to their structural features: PNCR1, PNCR2 and PNCR3